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Journal Article

Towards longer-lived metal-to-ligand charge transfer states of iron(II) complexes: An N-heterocyclic carbene approach.

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Canton,  S. E.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

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Citation

Liu, Y., Harlang, T., Canton, S. E., Chabera, P., Suarez-Alcantara, K., Fleckhaus, A., et al. (2013). Towards longer-lived metal-to-ligand charge transfer states of iron(II) complexes: An N-heterocyclic carbene approach. Chemical Communications, 49(57), 6412-6414. doi:10.1039/c3cc43833c.


Cite as: http://hdl.handle.net/11858/00-001M-0000-002D-806A-E
Abstract
A 9 ps (MLCT)-M-3 lifetime was achieved by a Fe-II complex based on C(NHC)boolean AND N(py)boolean AND C(NHC) pincer ligands. This is the longest known so far for any kind of complexes of this abundant metal, and increased by almost two orders of magnitude compared to the reference Fe-II bis-terpyridine complex.