Deutsch
 
Hilfe Datenschutzhinweis Impressum
  DetailsucheBrowse

Datensatz

DATENSATZ AKTIONENEXPORT
Zur Ablage hinzufügen
  Lokale TagsFreigabegeschichteDetailsÜbersicht

Freigegeben
Zeitschriftenartikel

X-ray photoelectron spectroscopy and near-edge X-ray absorption fine structure study of water adsorption on pyridine-terminated thiolate self-assembled monolayers

MPG-Autoren
/persons/resource/persons211638

Grunze,  Michael
Cellular Biophysics, Max Planck Institute for Medical Research, Max Planck Society;

Externe Ressourcen

https://pubs.acs.org/doi/pdf/10.1021/la047980b
(beliebiger Volltext)

https://doi.org/10.1021/la047980b
(beliebiger Volltext)

Volltexte (beschränkter Zugriff)
Für Ihren IP-Bereich sind aktuell keine Volltexte freigegeben.
Volltexte (frei zugänglich)
Es sind keine frei zugänglichen Volltexte in PuRe verfügbar
Ergänzendes Material (frei zugänglich)
Es sind keine frei zugänglichen Ergänzenden Materialien verfügbar
Zitation

Zubavichus, Y., Zharnikov, M., Yang, Y., Fuchs, O., Umbach, E., Heske, C., et al. (2004). X-ray photoelectron spectroscopy and near-edge X-ray absorption fine structure study of water adsorption on pyridine-terminated thiolate self-assembled monolayers. Langmuir, 20(25), 11022-11029. doi:10.1021/la047980b.


Zitierlink: https://hdl.handle.net/21.11116/0000-0001-ADA2-5
Zusammenfassung
Adsorption of water on self-assembled monolayers (SAMs) of 4-(4-mercaptophenyl)pyridine on gold at low temperatures under ultrahigh vacuum conditions is studied by synchrotron radiation X-ray photoelectron and absorption spectroscopy. Water adsorption induces a strong modification of the chemical state of the pyridine N atoms at the SAM/ice interface, indicative for strong H bonding and partial proton transfer between water molecules and pyridine moieties. Additionally, the initial molecular orientation within the SAM is changed upon formation of an adsorbed water multilayer.