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Journal Article

Electronic spectra and triplet state properties of superphane

MPS-Authors
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Schweitzer,  Dieter
Department of Molecular Physics, Max Planck Institute for Medical Research, Max Planck Society;

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Hausser,  Karl H.
Department of Molecular Physics, Max Planck Institute for Medical Research, Max Planck Society;

/persons/resource/persons231734

Vogler,  Helmut
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

/persons/resource/persons95446

Staab,  Heinz A.
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

External Resource

https://www.sciencedirect.com/science/article/pii/0301010486851473/pdf?md5=4deb1152e5681b0c8fc630897a34a442&pid=1-s2.0-0301010486851473-main.pdf
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https://doi.org/10.1016/0301-0104(86)85147-3
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Citation

Schweitzer, D., Hausser, K. H., Vogler, H., Staab, H. A., & Boekelheide, V. (1986). Electronic spectra and triplet state properties of superphane. Chemical Physics, 110(1), 93-101. doi:10.1016/0301-0104(86)85147-3.


Cite as: https://hdl.handle.net/21.11116/0000-0006-952B-2
Abstract
The emission and the zero-field splitting parameters D and E of the superphane 1 and the [25](1,2,3,4,5)-cyclophane 2 are investigated. The large number of six and five methylene bridges, respectively, leads to a more rigid molecular frame and to a smaller transanular distance as compared to other [2.2]cyclophanes. The experimental results exhibit characteristics features which are due to these unusual properties; they are discussed and compared with semi-empirical Π-electron calculations.