Enhancement of A′-site Mn3+ spin ordering by B-site Mn4+ substitution in 
quadruple perovskite PbMn3Cr3MnO12

Liu, Guangxiu; Zhou, Long; Zhou, Bowen; Ye, Xubin; Lu, Dabiao; Shen, Xudong; Qin, Shijun; Hu, Zhiwei; Chin, Yi-Ying; Lin, Hong-Ji; Chen, Chien-Te; Yu, Xiaohui; Long, Youwen

doi:10.1063/5.0051128

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Enhancement of A′-site Mn³⁺ spin ordering by B-site Mn⁴⁺ substitution in quadruple perovskite PbMn₃Cr₃MnO₁₂

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Hu, Zhiwei
Zhiwei Hu, Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Citation

Liu, G., Zhou, L., Zhou, B., Ye, X., Lu, D., Shen, X., et al. (2021). Enhancement of A′-site Mn³⁺ spin ordering by B-site Mn⁴⁺ substitution in quadruple perovskite PbMn₃Cr₃MnO₁₂. Applied Physics Letters, 118: 262403, pp. 1-5. doi:10.1063/5.0051128.

Cite as: https://hdl.handle.net/21.11116/0000-0008-E4EF-A

Abstract

An A-site ordered but B-site disordered quadruple perovskite oxide PbMn3Cr3MnO12 was synthesized by high-pressure and high-temperature methods. The compound crystallizes in space group Im-3 with the charge distribution of Pb2+Mn3+3Cr3+3Mn4+O12. Three antiferromagnetic phase transitions are found to occur at TN1 ≈ 155, TN2 ≈ 81, and TN3 ≈ 74 K, respectively, due to the complex B-site and A′-B intersite spin interactions. Compared with the isostructural LaMn3Cr4O12 with negligible A′-B intersite spin coupling, the substitution of Mn4+, which has identical electronic configuration to that of Cr3+ (t2g3), into the B site can introduce A′-B intersite spin interactions. As a result, the A′-site spin-related ordering temperature increases significantly, while the B-site one remains little changed in the current PbMn3Cr3MnO12. This work opens up a way to enhance the A′-site spin ordering temperature in quadruple perovskite oxides. © 2021 Author(s).