アイテム詳細

要旨

The oligomers of carbon suboxide, known as red carbon, exhibit a highly conjugated structure and semiconducting properties. Upon mild heat treatment, it transforms into a carbonaceous framework rich in oxygen surface terminations, called oxocarbon. In this study, we harness the abundant oxygen functionalities as anchors to create oxocarbon-supported nanohybrid electrocatalysts. Starting with single atomic Cu (II) strongly coordinated to oxygen atoms on red carbon, the Fehling reaction leads to the formation of Cu₂O clusters. Simultaneously, a covalent oxocarbon framework emerges via cross-linking, providing a robust support for Cu₂O clusters. Notably, the oxocarbon support effectively stabilizes Cu₂O clusters of very small size, ensuring their high durability in acidic conditions and the presence of ammonia. The synthesized material exhibits a superior electrocatalytic activity for nitrate reduction under acidic electrolyte conditions, with a high yield rate of NH4⁺ at 3.31 mmol h⁻¹ mgcat⁻¹ and a Faradaic efficiency of 92.5% achieved at a potential of -0.4 V (vs. RHE).