アイテム詳細

要旨

We theoretically and computationally investigate bulk photovoltaic effects, with a specific focus on shift-current and injection-current. Initially, we perform a numerical analysis of the direct current (dc) induced by a laser pulse with a one-dimensional model, utilizing mean-field theories such as time-dependent Hartree–Fock and time-dependent Hartree methods. Our numerical results, obtained with mean-field theories, reveal that the dc component of the current, as a second-order nonlinear effect, exists even after irradiation with linearly polarized light as a second-order nonlinear effect, indicating the generation of injection-current. Conversely, when we employ the independent-particle approximation, no injection-current is generated by linearly polarized light. To develop the microscopic understanding of injection-current within the mean-field approximation, we further analyze the dc component of the current with the perturbation theory, employing the mean-field approximations, the independent-particle approximation, and the exact solution of the many-body Schrödinger equation. The perturbation analysis clarifies that the injection-current induced by linearly polarized light under the mean-field approximations is an artifact caused by population imbalance, created through quantum interference from unphysical self-excitation pathways. Therefore, investigation of many-body effects on the bulk photovoltaic effects have to be carefully conducted in mean-field schemes due to potential contamination by unphysical dc current. Additionally, we perform the first-principles electron dynamics calculation for BaTiO₃ based on the time-dependent density functional theory, and we confirm that the above findings from the one-dimensional model calculation and the perturbation analysis apply to realistic systems.