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  {5,5′-Bis(di­ethyl­amino)-2,2′-[(2,2-di­methyl­propane-1,3-di­yl)bis­­(nitrilo­methanylyl­­idene)]diphenolato}dioxido­molybdenum(VI).

Kargar, H., & Kia, R. (2011). {5,5′-Bis(di­ethyl­amino)-2,2′-[(2,2-di­methyl­propane-1,3-di­yl)bis­­(nitrilo­methanylyl­­idene)]diphenolato}dioxido­molybdenum(VI). Acta Crystallographica Section E, 67(10): m1348. doi:10.1107/S1600536811035069.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-002C-17E0-8 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-002C-17E5-D
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Kargar, H., Author
Kia, R.1, Author           
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1Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society, ou_578564              

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 Abstract: In the title compound, [Mo(C27H38N4O2)O2], the MoVI atom is coordinated by two oxide O atoms and by two O and two N atoms of the tetra­dentate Schiff base ligand in a distorted octa­hedral geometry. The Mo—N bond trans to a terminal oxide group is significantly longer than the other Mo—N bond, which is attributed to the strong trans effect of the oxide O atom. The dihedral angle formed between the substituted benzene rings is 71.79 (14)°. One of the ethyl groups is disordered over two sets of sites, with a refined site-occupancy ratio of 0.588 (18):0.412 (18).

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Language(s): eng - English
 Dates: 2011-092011-10
 Publication Status: Issued
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 Rev. Type: Peer
 Identifiers: DOI: 10.1107/S1600536811035069
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Title: Acta Crystallographica Section E
Source Genre: Journal
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Pages: 10 Volume / Issue: 67 (10) Sequence Number: m1348 Start / End Page: - Identifier: -